Clusters, Couches minces et Nanomateriaux Biomateriaux Matériaux à Effet Coopératifs Intermétalliques et Systèmes Corrélés Publications
Hygiène et sécurité Thèses/Stages

Dr. Yann MOLARD

Maître de Conférences HDR.

coordonnées
activités de recherche


Yann Molard obtained his PhD degree in 2000 at the University Claude Bernard Lyon 1 (France) under the supervision of Pr. Helene Parrot-Lopez and Pr. Jean-Bernard Regnouf de Vains in the field of Supramolecular chemistry. He modified calixarene with polypyridinyl ligands and studied their complexation behaviour towards metallic cation. Then, he obtained a non permanent position of lecturer in the same university (1 year, 00/01) and worked on molecular modelling of catalysts grafted on oxyde surface with Dr. J. M. Basset. Later, he went to the engineering school INSA Lyon for another non permanent lecturer position (1 year, 02/03) and worked with Pr. Jean Francois Gerard and Dr. Jocelyne Galy(Laboratory of Macromolecular Material) on the molecular modelling of interactions between polymers and non-modified and modified silica surfaces.
He went back to supramolecular chemistry by taking during two years a post doctoral research associate position in the Jim Tucker's group in UK where he developped anthracene containing molecular photoswitchable receptors for neutral guest. This subject gave him the opportunity to collaborate with Dr. J.P. Desvergne and Dr. D. Bassani in Bordeaux where he spent around six months.

He joined the solid state chemistry and material team of the University Rennes 1 as lecturer in September 2005. His research interests are focused now on the modification of octahedral metallic clusters with organic or organometallic ligands in order to assemble them in an appropriate way to obtain new materials with specific properties. The behaviours of those nano organised materials depend on the interaction between clusters and ligands.

keywords: supramolecular chemistry, photochromism, molecular sensors, nanomaterial, hybrids, metallic cluster based material.


Other interest:
Computer and molecular modelisation, webdesign, music.

Selected publications

Clustomesogens: liquid crystal based transition metal clusters,
Y. Molard, F. Dorson, V. Circu, F. Artzner, S. Cordier,
Angew. Chem. Int. Ed., 2010, 49, 3351-3355

Red-NIR Luminescent Hybrid PMMA Containing Covalently Linked Octahedral Rhenium Metallic Clusters,
Y. Molard, F. Dorson, K. A. Brylev, M. A. Shestopalov, Y. Le Gal, S. Cordier, Y. V. Mironov, N. Kitamura, C. Perrin,
Chem. Eur. J., 2010, doi: 10.1002/chem.200902131

Electronic Effects and Absorbtion Properties of Supramolecular Assemblies Based on TTF-CH=CH-Py Ligands Coordinated to [Mo6Xi8]4+ Cluster Cores (X=Cl, Br, I) ,
G. Prabusankar, Y. Molard, S. Cordier, S. Gohlen, Y. Le Gal, C. Perrin, S. Kalahal, J. F. Halet, L. Houahab,
Eur. J. Inorg. Chem., 2009, 2153-2161

One pot synthesis and characterization of bi-functional phosphor-magnetic @SiO2 nanoparticles:controlled and structured association of Mo6 cluster units and gamma-Fe2O3 nanocrystals,
F. Grasset, F. Dorson, Y. Molard, S. Cordier, V. Demange, C. Perrin, V. Marchi-Artzner, H. Haneda,
Chem. Commun., 2008, 4729-4731

When metal atom clusters meet ZnO Nanocrystals: Novel ((n-C4H9)4N)2Mo6Br14@ZnO hybrid,
F. Grasset, Y. Molard, S. Cordier, F. Dorson, M. Mortier, C. Perrin, M. Guilloux-Viry, T. Sasaki, H. Haneda,
Adv. Mater., 2008, 20, 9, 1710-1715

Water-in-Oil Microemulsion Preparation and Characterization of Cs2[Mo6X14]@SiO2 Phosphor Nanoparticles Based on Transition Metal Clusters (X = Cl, Br, and I) ,
F. Grasset, F. Dorson, S. Cordier, Y. Molard, C. Perrin, A.-M. Marie, T. Sasaki, H. Haneda, Y. Bando, M. Mortier,
Adv. Mater., 2008, 20, 1, 143

Structural Effects on the Ground and Excited-state Properties of Photoswitchable Hydrogen-Bonding Receptors ,
Y. Molard, D. M. Bassani, J.-P. Desvergne, N. Moran, J. H. R. Tucker,
J. Org. Chem., 2006, 71, 22, 8523-8531

Selective electrochemical sensing of acidic organic molecules via a novel guest-to-host proton transfer reaction,
H. Miyaji, G. Gasser, Y. Molard, S. J. Green, S. M. Strawbridge and J. H. R. Tucker,
Chem Commun, 2005, 5355-5357

Photorelease of an Organic Molecule in Solution: Light-Triggered Blockage of a Hydrogen-Bonding Receptor Site ,
Y. Molard, D. M. Bassani, J. -P. Desvergne, P. N. Horton, M. B. Hursthouse, J. H. R. Tucker,
Angew. Chem. Int. Ed., 2005, 44, 7, 1072-1075

Surface Organometallic Chemistry of Main Group Elements: Selective Synthesis of Silica Supported [Si-O-B(C6F5)3]-[HNEt2Ph]+,
N. Millot, A. Cox, C. C. Santini, Y. Molard, J.M. Basset,
Chem. Eur. J., 2002, 8, n°6, 1438-1442

Molecular Scaffolds for di-metallic complexation: the synthesis and complexation properties of tetrakis-Terpyridinyl-calix[4]arene,
Y. Molard, H. Parrot-Lopez,
Tetrahedron Lett., 2002, 43, 6355-6358

Equipe Chimie du Solide et Matériaux, U.M.R. 6226 Sciences Chimiques de Rennes, Campus de Beaulieu, Bat. 10A, R.d.C. porte 49, Avenue du Général Leclerc, 35042 RENNES Cedex, France;
tel: +33 (0) 223 236 247; fax: +33 (0) 223 236 799.